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  8. 1H-Benzotriazol-1-yloxytris-(dimethylamino)-phosphonium Hexafluorphosphat, 98 %, Thermo Scientific Chemicals

1H-Benzotriazol-1-yloxytris-(dimethylamino)-phosphonium Hexafluorphosphat, 98 %, Thermo Scientific Chemicals

Product Code. 11443187
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Menge:
1 g
5 g
25 g
This item is not returnable. View return policy
This item is not returnable. View return policy

Description

CAS: 56602-33-6 | C12H22F6N6OP2 | 442.287 g/mol

1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
1H-Benzotriazol-1-yloxytris(dimethylamin)phosphoniumhexafluorphosphat wird als Reagenz für die Peptidkopplung, Laktonisierung, selektive Veresterung, Amidierung von Alfa-Aminosäuren ohne Racemisierung und Synthese von Magnolamid für antioxidative Aktivität und als Katalysator für 9-Acridincaroboxamid verwendet. Es wird auch als Vorläufer für die Synthese von Phenylestern aus Aminosäuren verwendet. Es dient als Ersatz für (Benzotriazol-1-yloxy)tris(dimethylamin)phosphoniumhexafluorphosphat (BOP)-Reagenz.

Löslichkeit
Löslich in Methanol, Ethanol und Dichlormethan. Unlöslich in Wasser.

Hinweise
Feuchtigkeits- und lichtempfindlich. Nicht kompatibel mit starken Oxidationsmitteln. Kühl lagern. Den Behälter dicht verschlossen halten.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 56602-33-6
Summenformel C12H22F6N6OP2
Molekulargewicht (g/mol) 442.287
MDL-Nummer MFCD00011948
InChI-Schlüssel MGEVGECQZUIPSV-UHFFFAOYSA-N
Synonym bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate
PubChem CID 151348
IUPAC-Name Benzotriazol-1-yloxy-tris(Dimethylamino)Phosphanium;Hexafluorphosphat
SMILES CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F

Specifications

Chemischer Name oder Material 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate
Schmelzpunkt ∼138°C (decomposition)
Menge 1 g
UN-Nummer UN1325
Beilstein 4287025
Formelmasse 442.29
Reinheit (%) 98%

RUO – Nur für Forschungszwecke

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